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Free Sunsilk Shampoo Samples are great. I have a whole drawer full of random shampoo samples. They come in handy when you are traveling (since they are all normally allowed in your carry on), for cleaning messes, or if you ever need to make a giant slip and slide (long story).
Funny Shampoo Commercial:
The NEW link (UPDATED JANUARY 8, 2009):
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Sample A Day posts samples daily that are free with no catch. We double check the offers to make sure they are real. Offers can expire quick so check back daily!
Nick Skeba helped cofound this site back in 2007. He lives in Chicago and loves free stuff! People are always asking him how he gets so many deals? He just tells them, Sample A Day! He writes a Coupon Site as well as this website.
Scott Aaronson also helped cofound this website and even though is a lawyer by day, he's still loves his free samples. Find him eating lunch from the sample ladies at Costco!